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Because of the correlation of the electron pairs, it is highly improbable that once the superconducting state has been entered, a pair will be scattered out of the flow (i.e. cause resistivity), since this would imply that all the electron pairs have to change their states. The wavefunctions of the electron-pairs are correlated by with the other pairs by a phase difference, meaning that the knowledge of the wavefunction at one place determines it at another. We will now examine this phase correlation.
The electron-pairs form a single state that can be described by
 |
(1) |
where
is the net momentum which is the same for all pairs and
the centre of mass.
Assuming a homogeneous current density, all electron-pairs in a superconductor have the same momentum and therefore have waves of the same wavelength. The superposition of a number of coherent waves of equal wavelength can be described by a single wave of a form
 |
(2) |
where
,
is the density of electron-pairs and P is the momemtum per pair.This wavefunction will theoretically stay in phase forever.
Phase changes occur due to the non-zero net momentum of the Cooper pairs, i.e. a non-zero wave vector
, where
. Inserting this into the expression for the wave, we can derive the difference in phase due to a supercurrent, flowing between X and Y, as
 |
(3) |
where
is the density of the electron pairs.
Applying an magnetic field changes the expression to
 |
(4) |
where
is the vector potential
.
This can be easily seen, since the canonical momentum
changes to
.
Next: The discreteness of the
Up: Introduction
Previous: The Superconducting state
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Barry Fitzgerald
2001-05-17